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The purpose of this work is to reveal the mechanism of WO₄²⁻ on surface passivation for Q235 carbon steel in tungstate solution.

In Na₂WO₄ solutions with the different concentrations of WO₄²⁻, the spontaneous passivation occurred on the surface of Q235 carbon steel when the concentration of WO₄²⁻ was up to 0.13 mmol/L, which was attributed to the formations of the inner deposition film and the outer adsorption film on the Q235 surface under the action of WO₄²⁻.

The inner deposition film presented a two-layer microstructure: the inside layer was composed of Fe₂O₃ mainly, and the outside layer comprised Fe(OH)2•nH₂O, Fe(OH)3•nH₂O, FeWO₄ and Fe₂(WO₄)3.

Both FeWO₄ and Fe₂(WO₄)3 repaired the defects in the outside layer of the inner deposition film; however, the outer adsorption film played a more important role in the surface passivation than the inner deposition film did.

The purpose of this paper is to reveal the mechanism of nitrite (NO_2⁻) for the surface passivation of carbon steels in acidic environments through investigating the influences of 0.01 mol/L NaNO₂ addition on the corrosion and passivation behaviors of Q235 carbon steel in acidic phosphate buffer (APB) solutions (pH 2 to 6).

The electrochemical techniques including open circle potential evolution, potentiodynamic polarization, electrochemical impedance spectroscopy and cyclic voltammetry were applied.

In APB solutions without NO_2⁻, the Q235 steel presented the electrochemical behaviors of activation (A), activation-passivation-transpassivation and self-passivation-transpassivation at pH 2 to 4, pH 5 and pH 6, respectively; the corrosion rate decreased with the up of pH value, and the surface passivation occurred in the pH 5 and pH 6 solutions only: the anodic passivation at pH 5 and the spontaneous passivation at pH 6.

In APB solutions without NO_2⁻, the corrosion rate decreased with the up of pH value, and the surface passivation occurred in the pH 5 and pH 6 solutions only: the anodic passivation at pH 5 and the spontaneous passivation at pH 6. With the addition of 0.01 mol/L NaNO₂, into APB solutions, the variation of corrosion rate showed the same rule, but the surface passivation occurred over the whole acidic pH range, including the anodic passivation at pH 2 to 4 and the spontaneous passivation at pH 5 to 6.

A chromate conversion coating was prepared on the surface of bare AA2024 aluminum alloy by direct immersion in the chromating treatment bath, and the corrosion behavior of chromated AA2024 aluminum alloy in 3.5 per cent NaCl solution was studied by electrochemical measurement and microstructural observation.

According to the polarization curve test and the scanning electron microscope observation, the corrosion evolution of chromated AA2024 in 3.5 per cent NaCl solution was divided into the following three stages: coating failure, pitting corrosion and intergranular corrosion (IGC).

In the first stage, the chromate coating degraded gradually due to the combined action of chloride anions and water molecules, resulting in the complete exposure of AA2024 substrate to 3.5 per cent NaCl solution. Subsequently, in the second stage, chloride anions adsorbed at the sites of θ phase (Al2Cu) and S phase (Al2CuMg) on the AA2024 surface preferentially, and some corrosion pits initiated at the above two sites and propagated towards the deep of crystal grains. However, the propagation of a pit terminated when the pit front arrived at the adjacent grain boundary, where the initiation of IGC occurred.

Finally, in the third stage, the corrosion proceeded along the continuous grain boundary net and penetrated the internal of AA2024 substrate, resulting in the propagation of IGC. The related corrosion mechanisms for the bare and the chromated AA2024 were also discussed.

The aim of this work was to propose a method to prepare composite phosphate conversion coating (CPCC), including ternary phosphate conversion coating (TPCC) and binary phosphate conversion coatings (BPCC), with one-step chemical conversion and to reveal and compare the corrosion resistance between TPCC and BPCC.

In this work, a calcium–manganese–zinc (Ca–Mn–Zn) TPCC was prepared on the surface of magnesium alloy (MA) AZ91D with one-step chemical conversion method; for Ca-Mn-Zn@TPCC, its microstructure was characterized with scanning electron microscope observation and scanning tunneling microscope detection, and its composition was characterized with energy dispersion spectroscopy and X-ray photoelectron spectroscopy analyses. Particularly, the corrosion resistance of Ca-Mn-Zn@TPCC and its comparison with Ca–Mn, Ca–Zn and Mn–Zn BPCCs were clarified with electrochemical and immersion measurements.

Ca-Mn-Zn@TPCC, which was composed of Ca, Mn, Zn, P and O, exhibited a mud-shaped with cracks microstructure, and the average crack width, terrain fluctuation and coating thickness were 0.61 µm, 23.78 nm and 2.47 µm, respectively. Ca-Mn-Zn@TPCC provided good corrosion resistance to MA AZ91D; in NaCl solution, the total degradation of Ca-Mn-Zn@TPCC consumed eight days; corrosion products with poor adhesion peeled out from Ca-Mn-Zn@TPCC-coated MA AZ91D spontaneously. Besides, the corrosion resistance of Ca-Mn-Zn@TPCC was better than that of Ca-Mn@BPCC, Ca-Zn@BPCC or Mn-Zn@BPCC.

The successful preparation of Ca-Mn-Zn@TPCC on MA AZ91D surface confirmed the proposed method to prepare CPCC with one-step chemical conversion was feasible; at the same time, it was further confirmed that for phosphate conversion coating, ternary coating had better corrosion resistance than binary coating did.

The purpose of this paper is to investigate the impact of cloud computing (CC) on supply chain management (SCM).

The paper is conceptual and based on a literature review and conceptual analysis.

Today, digital technology is the primary enabler of supply chain (SC) competitiveness. CC capabilities support competitive SC challenges through structural flexibility and responsiveness. An Internet platform based on CC and a digital ecosystem can serve as “information cross-docking” between SC stakeholders. In this way, the SC model is transformed from a traditional, linear model to a platform model with the simultaneous cooperation of all partners. Platform-based SCs will be a milestone in the evolution of SCM – here conceptualised as Supply Chain 3.0.

Currently, SCs managed holistically in cyberspace are rare in practice, and therefore empirical evidence on how digital technologies impact SC competitiveness is required in future research.

This research generates insights that can help managers understand and develop the next generation of SCM with the use of CC, a modern and commonly available Information and Communication Technologies (ICT) tool.

The paper presents a conceptual basis of how CC enables structural flexibility of SCs through easy, real-time resource and capacity reconfiguration. CC not only reduces cost and increases flexibility but also offers an effective solution for disruptive new business models with the potential to revolutionise current SCM thinking.